I have an English class and a PE class on Wednesday afternoon.
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I have an English class and a PE class on Wednesday afternoons.
这是将这种上课情况当作你的常态。若是讲即将来到的星期三,则是:
I'll have an English class and a PE class this Wednesday afternoon.
查了下,星期三下午可以说成Wednesday afternoon, 于是作了点修改。